- New simulations indicate that swirling ammonia in combustion chambers can help reduce harmful emissions – insight that may help on-going efforts to develop ammonia as a carbon-free fuel source.
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Researchers in Japan have identified a way to reduce harmful emissions produced by ammonia fuel. It involves swirling the gas with air as part of the power generation process. The finding helps advance research into ammonia as an alternative to carbon-based fuels for cars, airplanes, and power generation facilities.
Ammonia (NH3) is a compound that contains one nitrogen and three hydrogen atoms. It is under investigation as an alternative fuel source for several reasons. It contains a lot of hydrogen, but is less expensive and less flammable than pure hydrogen, making it safer to transport. Production plants already exist because ammonia is widely used in fertilizers.
So far, ammonia has been considered as a fuel when blended with gasoline, diesel, hydrogen and methane fuels to reduce the proportion of carbon-based fuels and their emissions that contribute to climate change. Developing ammonia as a pure fuel source remains a challenge, in part because relatively high levels of harmful nitric oxide emissions are produced during the combustion process.
Nitric oxide is known to be harmful to human health, contributes to ozone depletion, and when it reacts with other compounds, contributes to acid rain and atmospheric warming.
A team from the Institute of Fluid Science at Tohoku University in Japan used supercomputers to run 'large eddy simulations' to analyse how ammonia fuel behaves under different combustion conditions, and to see if it is theoretically possible to reduce nitric oxide emissions.
Specifically, they analysed what happened when ammonia was swirled together with air inside a theoretical combustion chamber under different pressures. They compared the results with those of ammonia and air premixed before entering the combustion chamber, which is known to produce fewer nitric oxide emissions at high fuel to air ratio conditions.
They found that swirling not one, but two streams of ammonia gas with one stream of air reduced nitric oxide emissions to levels on par with premixed processes. Making the volume of the two ammonia streams between the innermost and outermost swirlers uneven—60 percent and 40 percent of the total injected fuel, respectively—led to a more even distribution of fuel and air throughout the combustion chamber, which produced lower nitric oxide emissions.
Still, emission levels were higher than the Japanese environmental regulations for gas power turbines. The researchers plan to next test if injecting air downstream of the combustor further reduces emissions.
- Ammonia is anticipated to be a hydrogen carrier with high hydrogen content. In this research, a prototype combustion unit was built that enabled kerosene (liquid) and ammonia (gas) to be fed, and ammonia was combusted in a gas-turbine generator. This can be said to be a great step forward for ammonia in energy-use technology, and power generation using 100 % ammonia is anticipated.
- In recent years, expectations are rising for hydrogen and hydrogen carriers as a medium for storage and transportation of energy in the mass introduction and use of renewable energy. Storage and transport of hydrogen is an important issue since hydrogen is a gas under normal temperature and pressure. Hydrogen carriers are mediums that convert hydrogen into chemical substances containing large amounts of hydrogen, to facilitate storage and transport. Hydrogen carriers include organic hydrides that are used by absorption and desorption of hydrogen to and from organic solvents (methylcyclohexane, etc.) and ammonia synthesized from nitrogen and hydrogen that is used by direct combustion. Ammonia is gaining particular attention as a hydrogen carrier that does not contain any carbon atoms and has a high hydrogen ratio. Expectations are on the rise for its use as a power-generating fuel. Since ammonia will generate mainly water and nitrogen on combustion, replacing a part of conventional fuel with ammonia will have a large effect in reducing carbon dioxide emissions.
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