- As the only alkaline gas in the atmosphere, ammonia can react with sulfur dioxide and nitrogen oxides to form secondary fine particles, accelerating the generation of atmospheric haze. Ammonia is therefore considered as a catalyst and accelerator for the widespread haze pollution problem in China. In the past decade, China has made great progress in the prevention and control of atmospheric sulfur dioxide and nitrogen oxide pollution, but little has been done in terms of ammonia emissions control.
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Compiling an emissions inventory is an important basis for ammonia control. Although there are some existing global or national emission inventories, they are not very applicable to regional-scale ammonia emission reduction policies due to the lack of specific regional information. Professor Weishou Shen's research group at Nanjing University of Information Science and Technology (NUIST) investigated ammonia emissions from agriculture in Jiangsu Province from 2000 to 2017 based on the emissions factor method, and the findings have been published in Atmospheric and Oceanic Science Letters.
"Jiangsu is where our research team is based, and it happens that this province ranks first in ammonia emissions from agriculture in key areas of national air pollution control in China," explains Shen. "We therefore feel it's our duty to investigate the characteristics and trend of change of ammonia emissions from agriculture here."
The team selected five regional representative nitrogen fertilizers and four typical livestock types and calculated their corresponding emission factors to investigate the characteristics and trends of agricultural ammonia emissions in Jiangsu from 2000 to 2017. They found that ammonia emissions from agriculture were mainly contributed by livestock and poultry farming (78.08%) and nitrogen fertilizer application (21.92%), and presented a fluctuating interannual trend during the study period.
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Researchers in Japan have identified a way to reduce harmful emissions produced by ammonia fuel. It involves swirling the gas with air as part of the power generation process. The finding helps advance research into ammonia as an alternative to carbon-based fuels for cars, airplanes, and power generation facilities.
Ammonia (NH3) is a compound that contains one nitrogen and three hydrogen atoms. It is under investigation as an alternative fuel source for several reasons. It contains a lot of hydrogen, but is less expensive and less flammable than pure hydrogen, making it safer to transport. Production plants already exist because ammonia is widely used in fertilizers.
So far, ammonia has been considered as a fuel when blended with gasoline, diesel, hydrogen and methane fuels to reduce the proportion of carbon-based fuels and their emissions that contribute to climate change. Developing ammonia as a pure fuel source remains a challenge, in part because relatively high levels of harmful nitric oxide emissions are produced during the combustion process.
Nitric oxide is known to be harmful to human health, contributes to ozone depletion, and when it reacts with other compounds, contributes to acid rain and atmospheric warming.
A team from the Institute of Fluid Science at Tohoku University in Japan used supercomputers to run 'large eddy simulations' to analyse how ammonia fuel behaves under different combustion conditions, and to see if it is theoretically possible to reduce nitric oxide emissions.
Specifically, they analysed what happened when ammonia was swirled together with air inside a theoretical combustion chamber under different pressures. They compared the results with those of ammonia and air premixed before entering the combustion chamber, which is known to produce fewer nitric oxide emissions at high fuel to air ratio conditions.
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They found that swirling not one, but two streams of ammonia gas with one stream of air reduced nitric oxide emissions to levels on par with premixed processes. Making the volume of the two ammonia streams between the innermost and outermost swirlers uneven—60 percent and 40 percent of the total injected fuel, respectively—led to a more even distribution of fuel and air throughout the combustion chamber, which produced lower nitric oxide emissions.
Still, emission levels were higher than the Japanese environmental regulations for gas power turbines. The researchers plan to next test if injecting air downstream of the combustor further reduces emissions.
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